Nine-time champions Liverpool will play Fulham in their Carabao Cup semifinal in January, while Championship side Middlesbrough will take on Chelsea.
The draw was held moments after Liverpool's 5-1 rout of West Ham United on Wednesday to claim the last of the fourth berths.
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The semifinal first legs will be played the week of Jan. 8, and the second legs beginning Jan. 22. The final is Feb. 25 at Wembley Stadium.
Liverpool clinched a record-19th semifinal berth, and their nine League Cup titles are also a record.